Xie Yu of China struck gold in a dream Olympic debut, displaying the poise of a veteran in the men's 10m air pistol event on Sunday.
South Korea dominated the women's event claiming the gold and silver through Oh Ye-jin and Kim Ye-ji respectively.
Manu Bhaker's bronze is India's first medal in the Paris Games.
After China won the 10m air rifle mixed team event on Saturday, Xie (240.9) mined another gold from the Chateauroux Shooting Center, beating Italian Federico Nilo Maldini (240) who took the silver medal.
Paolo Monna (218.6) claimed bronze with clear daylight between the top three and the rest of the field.
"If I hadn't won, this may have been my biggest regret," Xie said. "It is very difficult to be selected for China for the Olympics, so to be able to stand here today, on this higher stage, is very significant for me."
Xie carried a wafer-thin cushion of 0.4 going into the final shot after Maldini had reduced the gap in the elimination section.
The Italian lost his momentum at the last minute, however, and stood gazing at the floor after signing off with a modest 9.5.
Xie scored 10 to seal the gold and flashed a shy smile as his teammates in bright red and white erupted in the stands.
"We both made some silly mistakes but we have no regrets whatsoever," Maldini said, referring to compatriot Monna.
"I had good vibes since the beginning of the final," Monna said. "It's certainly emotional and a very rare one because we are friends. This is the first time we're on the podium together and it is the most important one."
Shooting resumes with the women's air rifle event at 3:30 a.m. ET on Monday, July 29.
RESULTS (men's 10m air pistol)
RESULTS (women's 10m air pistol)